Disodium tris(dioxidomolybdenum) bis(diarsenate)
Identifieur interne : 000373 ( Main/Exploration ); précédent : 000372; suivant : 000374Disodium tris(dioxidomolybdenum) bis(diarsenate)
Auteurs : Raja Jouini [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
The asymmetric unit of the title compound, Na2(MoO2)3(As2O7)2, is composed of two cyclic MoAs2O11 units and an MoO6 corner-sharing octahedron. The anionic framework can be decomposed into two types of layers,
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DOI: 10.1107/S1600536812010069
PubMed: 22589750
PubMed Central: 3343776
Affiliations:
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The anionic framework can be decomposed into two types of layers, <italic>viz.</italic> MoO<sub>2</sub>As<sub>2</sub>O<sub>7</sub> and Mo<sub>2</sub>As<sub>2</sub>O<sub>14</sub>, which use mixed Mo—O—As and As—O—Mo bridges to achieve a new three-dimensional structure with two types of large channels in which the Na<sup>+</sup> cations are located. Two O atoms are disordered and are located in two positions close to their initial positions with occupancy ratios of 0.612 (17):0.388 (17) and 0.703 (12):0.298 (12).</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>Tunisie</li></country></list><tree><country name="Tunisie"><noRegion><name sortKey="Jouini, Raja" sort="Jouini, Raja" uniqKey="Jouini R" first="Raja" last="Jouini">Raja Jouini</name></noRegion><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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